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基于磁铁矿和赤铁矿混合配比的高品级直接还原球团的制备

Preparation of high-grade direct reduction pellets based on magnetic-hematite blending

  • 摘要: 为应对"双碳"战略下钢铁工业绿色转型的迫切需求, 气基竖炉直接还原技术凭借其显著的减碳潜力已成为该领域重点发展方向, 其中高品质直接还原(DR)球团的制备是该技术核心环节。目前研究多集中于磁铁矿球团, 而针对赤铁矿基球团, 尤其是磁铁矿和赤铁矿混合配比制备球团的系统研究仍较为缺乏。本研究以高品位赤铁矿(H矿)与磁铁矿(M矿)为原料, 系统探究了适用于气基竖炉生产要求的直接还原球团制备工艺。设计了4种磁铁矿和赤铁矿混合配比方案(B1、B2、B3、B4), 通过造球与焙烧试验, 优化氧化球团制备的热工制度。研究结果表明, 在适宜的热工制度下, 各配比方案均能制备出抗压强度高于2 800 N/个、全铁品位(质量分数)超过67.5%、有害元素含量低、碱度为0.3的优质氧化球团。基于Midrex工艺的冶金性能测试显示, 所有配比的氧化球团还原指数达到85%~90%, 还原膨胀指数均低于11%, 低温还原粉化指数均小于2.5%, 金属化率均超过93%, 各项指标满足Midrex气基竖炉直接还原工艺要求。本研究证实采用磁铁矿和赤铁矿混合配比制备高品级DR球团的可行性, 不仅丰富了直接还原球团的原料体系, 还为降低气基竖炉原料成本、拓宽优质球团矿资源渠道提供了重要的技术支撑, 对推动气基竖炉直接还原技术的规模化应用具有积极意义。

     

    Abstract: In response to the urgent need for the green transformation of iron and steel industry under the "dual carbon" strategy, gas-based shaft furnace direct reduction technology has emerged as a critical development direction due to its significant carbon reduction potential. The preparation of high-grade direct reduction (DR) pellets represents a core link of this technology. Current research mainly focuses on magnetite pellets while systematic studies on hematite-based pellets especially those prepared by mixing magnetite and hematite have remained relatively insufficient. This study took high-grade hematite (H ore) and magnetite (M ore) as raw materials and systematically explored the preparation process of direct reduction pellets suitable for the production requirements of gas-based shaft furnaces. Four magnetite-hematite blending schemes (B1, B2, B3, B4) were designed.Through systematic pelletizing and roasting experiments, the thermal regime for oxidized pellets preparation was optimized. The results demonstrate that under the appropriate thermal regime, all blending schemes can produce high-quality oxidized pellets with a basicity of 0.3, which are characterized by a compressive strength higher than 2 800 N per pellet, a total iron grade (mass fraction) of over 67.5%, and low contents of harmful elements. Simulated metallurgical performance tests based on the Midrex process show that the reduction index of all blended oxidized pellets reaches 85%-90%, the reduction swelling index is all below 11%, the low-temperature reduction degradation index is less than 2.5%, and the metallization rate exceeds 93%, with all indicators meeting the technical requirements of the Midrex gas-based shaft furnace direct reduction process. This study confirms the feasibility of preparing high-grade DR pellets from magnetite-hematite blends. It not only enriches the raw material system for DR pellet production, but also provides important technical support for reducing the raw material cost of gas-based shaft furnaces and expanding the supply channels of high-quality pellet ore resources. It has positive significance for promoting the large-scale application of gas-based shaft furnace direct reduction technology.

     

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