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钢渣中磷、铁提取的研究现状及应用进展

Research status and application progress of phosphorus and iron extraction from steel slag

  • 摘要: 钢渣是炼钢过程产生的大宗固体废弃物, 产量巨大但综合利用率较低, 造成巨大的资源浪费和环境污染。随着社会对钢渣回收的广泛关注和相关技术的创新发展, 研究者围绕钢渣中有价元素分离回收和高值化、绿色化利用开展了大量研究, 理论研究与相关工艺技术均取得了显著进展。本文梳理了国内外近年来有关钢渣中磷、铁元素提取分离的研究成果, 首先介绍了钢渣中磷、铁的赋存形态与分布特征, 综述转炉钢渣中磷、铁分离提取与回用研究现状, 分析不同技术的原理、特性和适用范围, 同时探讨了温度、钢渣粒度等技术参数对分离回收效果的影响, 以及制约各种技术推广应用的关键问题。钢渣中磷提取方法主要分为化学浸出法、物理分离法(包括磁选法、浮选法)和生物浸出法; 铁提取方法分为磁选法和还原法。通过对回收利用技术的总结对比可知, 回收效率、成本管控与污染治理是当前制约钢渣中磷、铁资源化回收利用的核心问题。最后, 对相关技术的未来发展方向进行了展望, 为钢渣的全量回收和高值化利用提供理论和技术参考, 推动钢铁行业高质量可持续发展。

     

    Abstract: Steel slag is a bulk solid waste produced in the steelmaking process with a huge output but low comprehensive utilization rate leading to great resource waste and environmental pollution. With the widespread attention to steel slag recovery and the innovative development of related technologies, researchers have carried out extensive studies on the separation, recovery, high-value and green utilization of valuable elements in steel slag and remarkable progress has been achieved in both theoretical research and related process technologies. This paper sorts out the research achievement on the extraction and separation of phosphorus and iron from steel slag at home and abroad in recent years. Firstly, it introduces the occurrence form and distribution characteristics of phosphorus and iron in steel slag, reviews the research status of the separation, extraction and reuse of phosphorus and iron from converter steel slag, analyzes the principles, characteristics and application scope of different technologies, discusses the influence of technical parameters such as temperature and steel slag particle size on the separation and recovery effect, and indentifies the key problems restricting the popularization and application of various technologies. The extraction methods of phosphorus from steel slag are mainly divided into chemical leaching, physical separation (magnetic separation, flotation) and biological leaching. The extraction methods of iron are divided into magnetic separation method and reduction method. Through the summary and comparison of recycling technologies, recovery efficiency, cost control and pollution control are the core problems restricting the resource recovery of phosphorus and iron from steel slag at present. Finally, the future development direction of related technologies is prospected, which provides theoretical and technical reference for the full recovery and high-value utilization of steel slag and promotes the high-quality and sustainable development of the iron and steel industry.

     

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