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锡二次资源高效回收锡工艺技术现状及展望

Technology status and prospect of efficient tin recovery from tin secondary resources

  • 摘要: 锡作为重要的战略资源, 凭借优良的物理化学性能在众多领域中有不可替代的应用。易选锡资源日益枯竭, 而难处理锡矿回收率低, 导致锡资源供应压力日益凸显。提高含锡二次资源的综合回收利用率, 既可缓解锡资源供应压力, 也有助于减少其对环境的影响。本文聚焦于锡中矿和尾矿、废弃线路板、钨冶炼渣、锡合金废料、锡阳极泥等含锡二次资源, 分析全球锡资源分布、消费情况, 详细综述不同锡二次资源回收锡的工艺技术现状, 结合作用机理, 深入对比湿法、火法、微生物浸出、联合工艺等存在的优劣势, 以及在工业应用中的情况。研发短流程、高效回收锡的工艺方法, 为企业提升经济效益。在此基础上, 总结了当前锡行业在二次资源利用方面面临的主要技术难题, 如锡回收冶炼及精炼提纯工艺流程冗长、加工成本高等弊端, 这些因素制约了行业的可持续发展。未来开发锡二次资源的方向是制备高端价值化产品以及锡酸钠、硫化亚锡等高纯度产品, 提升废料的效益。本研究可为锡行业的良性循环发展提供参考借鉴。

     

    Abstract: As an important strategic resource, tin has irreplaceable applications in various fields due to its excellent physical and chemical properties. The gradual depletion of easily beneficiable tin resources and the low recovery efficiency of refractory tin ores increasingly aggravate the supply pressure of tin resources. Improving the comprehensive recovery and utilization efficiency of tin-bearing secondary resources can not only relieve the supply pressure of tin resources, but also reduce the corresponding environmental impact. This paper focuses on typical tin-bearing secondary resources, including tin middlings and tailings, waste printed circuit boards, tungsten smelting slag, tin alloy waste, and tin anode slime. The global distribution and consumption characteristics of tin resources are analyzed, and the current technical status of tin recovery processes for different tin secondary resources is comprehensively reviewed. Combined with the corresponding reaction mechanisms, the advantages, disadvantages and industrial application status of hydrometallurgy, pyrometallurgy, microbial leaching and combined processes are systematically compared. The development of short-process and high-efficiency tin recovery technologies helps improve the economic benefits of enterprises. On this basis, this study summarizes the major technical bottlenecks restricting the sustainable development of the tin secondary resource utilization industry, including lengthy technical processes and high processing costs in tin smelting, refining and purification. Future development directions of tin secondary resource utilization focus on the preparation of high-value-added products and high-purity products such as sodium stannate and stannous sulfide, so as to improve the utilization benefit of tin waste materials. This research provides a reference for the virtuous cycle and sustainable development of the tin industry.

     

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