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稀土基SCR脱硝催化剂的研究进展与应用前景

Research progress and application prospects of rare earth-based SCR denitration catalysts

  • 摘要: 铁矿粉烧结工序是钢铁工业氮氧化物(NOx)的核心排放源, 所产生烟气具有低温、高湿、高硫等特征, 并富集碱金属、重金属等多种有毒物质, 对脱硝技术工况适配性与催化剂的综合性能提出了更高要求。现阶段非稀土基氨气选择性催化还原(NH3-SCR)脱硝催化剂普遍存在低温活性欠佳、抗毒化能力不足、工业运行稳定性差等问题, 难以长期满足烧结烟气NOx超低排放要求, 成为制约钢铁行业绿色低碳发展的关键瓶颈。中国拥有丰富的稀土资源, 稀土元素因独特的4f电子构型, 具备优异的氧化还原性能与表面酸性调控能力, 为选择性催化还原(SCR)脱硝催化剂性能优化提供了有力支撑。本文系统梳理了钢铁烧结烟气的多组分污染特征与现有脱硝工业实际治理现状, 明确了传统脱硝技术在工业应用中的短板; 剖析了V-Ti基、Mn基、Cu基、Fe基等非稀土基催化剂的实验室性能与工业应用局限, 重点阐述了稀土改性各类非稀土基催化剂的技术路径、核心优势与作用机理, 并总结了稀土改性催化剂当前存在的固有劣势; 聚焦稀土基SCR催化剂的工业应用实践, 验证了其工业化应用价值与实际运行问题; 最后结合成本、规模化制备等实际因素并分析其应用前景, 以期为适配烧结烟气复杂工况的稀土基SCR催化剂规模化应用提供理论参考与实践指引, 助力钢铁行业NOx超低排放与"双碳"目标落地实施。

     

    Abstract: Iron ore sintering serves as the primary emission source of nitrogen oxides (NOx) in the iron and steel industry. The flue gas generated from this process features low temperature, high humidity and high sulfur content, and contains various toxic substances such as alkali metals and heavy metals, which put forward higher requirements for the working condition adaptability of denitration technologies and the comprehensive performance of catalysts. At present, non-rare earth-based NH3-SCR denitration catalysts generally exhibit poor low-temperature activity, insufficient poisoning resistance and inferior industrial operation stability. These catalysts cannot meet the long-term ultra-low NOx emission standards for sintering flue gas, which becomes a key bottleneck restricting the green and low-carbon development of the iron and steel industry. China is endowed with abundant rare earth resources. With unique 4f electron configurations, rare earth elements possess excellent redox properties and superior surface acidity regulation capability, which provides strong support for the performance optimization of SCR(Selective Catalytic Reduction)denitration catalysts. This paper systematically sorted out the multi-component pollution characteristics of steel sintering flue gas and the current status of industrial denitration treatment, and clarified the deficiencies of traditional denitration technologies in practical industrial application. The laboratory performance and industrial application limitations of various non-rare earth-based catalysts including V-Ti-based, Mn-based, Cu-based and Fe-based catalysts were analyzed. This study emphatically elaborated the technical routes, core advantages and action mechanisms of rare earth modification for different non-rare earth-based catalysts, and summarized the inherent defects of existing rare earth-modified catalysts. Focusing on the industrial application practices of rare earth-based SCR catalysts. This review verified their industrial application values and sorted out the practical operational problems. Finally, this paper analyzes the application prospects of such catalysts by combining practical factors including cost control and large-scale preparation.The research aims to provide theoretical reference and practical guidance for the large-scale engineering application of rare earth-based SCR catalysts applicable to the complex working conditions of sintering flue gas, and promote the realization of ultra-low NOx emissions and the achievement of the "dual carbon" goals in the iron and steel industry.

     

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