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稀土处理高强度低合金钢的研究进展及展望

Research progress and prospects of rare earth treatment of high-strength low-alloy steel grades

  • 摘要: 稀土元素是钢铁工业不可或缺的微量添加剂。通过精准调控钢中夹杂物的形貌、尺寸与分布, 稀土处理能够延长钢材寿命、降低缺陷率、提升环境友好性, 从而满足高强度低合金钢的高性能与可持续发展需求。为实现稀土的有效利用, 提升钢材的综合性能, 相关研究者围绕稀土元素改性钢中夹杂物开展了大量工作。首先, 基于热力学分析和第一性原理, 阐明了稀土改性夹杂物的自发驱动力和原子尺度机制。从单一稀土添加和复合稀土添加两方面分析了稀土添加对夹杂物形貌、尺寸及分布的改性机制和演变规律, 进一步分析了重稀土Y和轻稀土La与Ce等在原子尺度方面处理效果存在的差异。稀土元素能够将钢中粗大、不规则的Al2O3和MnS等夹杂物转变为细小、弥散、球状的Ce2O2S、LaAlO3等稀土氧硫化物, 显著提高钢的强度、韧性和塑性, 同时改善夹杂物的点蚀电位, 使其接近钢基体电位, 增强耐局部腐蚀性能。最后, 基于稀土改性钢中夹杂物技术的研究现状, 对未来稀土处理高强度低合金钢中夹杂物的发展趋势进行了展望。结合复合添加的协同优势, 提出了优化稀土配比和添加顺序的创新方向, 为稀土处理高强度低合金钢在桥梁建设、船舶制造、油气输送管线及建筑工程等领域的应用提供新思路, 推动钢铁行业的高性能和可持续发展。

     

    Abstract: Rare earth elements serve as indispensable trace additives in the steel industry. By precisely regulating the morphology, size and distribution of inclusions within steel, rare earth treatment can extend the service life of steel, reduce defect rates and enhance environmental friendliness, thus meeting the demands for high performance and sustainable development of high-strength low-alloy steels. To achieve the effective utilisation of rare earth elements and improve the comprehensive properties of steel, researchers carried out extensive research on the modification of inclusions in steel with rare earth elements. Firstly, based on thermodynamic analysis and first-principles calculations, the spontaneous driving force and atomic-scale mechanism of rare earth-modified inclusions were elucidated. The modification mechanisms and evolution patterns of inclusion morphology, size, and distribution under rare earth addition were analyzed from two aspects including single rare earth addition and composite rare earth addition. Furthermore, the differences in treatment effects at the atomic scale between heavy rare earth Y and light rare earths such as La and Ce were analyzed. Rare earth elements can transform coarse and irregular inclusions such as Al2O3 and MnS in steel into fine, dispersed and spherical rare earth oxysulfides such as Ce2O2S and LaAlO3. This transformation significantly improves the strength, toughness and ductility of steel. It also improves the pitting potential of inclusions to make them close to the potential of the steel matrix thus enhancing the local corrosion resistance. Finally, based on the current research status of inclusion modification technology in rare earth-modified steel, the future development trend of inclusion treatment in high-strength low-alloy steels by rare earth elements is prospected. Combining the synergistic advantages of composite addition, an innovative direction for optimizing the ratio and addition sequence of rareearth elementss is proposed. This provides new ideas for the application of rare earth-treated high-strength low-alloy steels in fields such as bridge construction, shipbuilding, oil and gas transmission pipelines and construction engineering, and promotes the high performance and sustainable development of the steel industry.

     

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