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高炉喷吹生物质的现实难题与解决路径

Practical challenges and solutions for injection of biomass into blast furnaces

  • 摘要: 在钢铁行业低碳转型与“双碳”目标背景下,探寻低碳清洁替代燃料、降低高炉炼铁碳排放已成为冶金领域重要研究课题。生物质作为典型碳中性可再生燃料,在高炉喷吹过程中具备良好减排效益,是钢铁行业发展低碳冶金的重要技术路径。但生物质存在碱金属含量偏高、可磨性差、能量密度差等问题,加之预处理工艺不完善、经济性不足,极大限制了其工业化大规模喷吹应用。本文以高炉喷吹用生物质为研究对象,系统剖析生物质喷吹面临的核心现实难题与内在作用机理,阐明生物质中钾、钠等碱金属在高炉高温体系内易发生气化迁移并形成富集循环,进而破坏焦炭微观结构、加剧焦炭冶金性能劣化;同时指出生物质组分构成的致密三维网络结构是其可磨性差的关键原因。针对上述技术瓶颈,本文系统梳理超声空化脱碱、烘焙预处理、蒸汽爆破、水热炭化等提质路径的工艺特点及应用局限,并提出了一种脱碱-助磨协同处理新技术,依托绿色可回收助剂,实现单一步骤同步完成碱金属深度脱除与可磨性同步提升。试验结果表明,该技术可将生物质碱金属总量控制在高炉喷吹标准范围内,粒度指标显著改善,相比传统工艺具备明显成本优势。研究证实,通过单一技术优化或多工艺耦合,可使生物质各项指标满足高炉喷吹工艺要求,具备大规模替代煤粉的应用潜力,为生物质高炉应用提供支撑。

     

    Abstract: Against the background of the low-carbon transformation of the iron and steel industry and the national dual-carbon goals, exploring low-carbon and clean alternative fuels and reducing carbon emissions from blast furnace ironmaking have become important research topics in the metallurgical field. As a typical carbon-neutral and renewable fuel, biomass exhibits excellent emission reduction benefits in blast furnace injection and acts as a vital technical route for the development of low-carbon metallurgy in the steel industry. However, biomass has the problems of high alkali metal content, poor grindability and low energy density. Combined with imperfect pretreatment processes and poor economic efficiency, the above problems severely limit its large-scale industrial application in blast furnace injection. This paper took biomass for blast furnace injection as the research object, systematically analyzed the core practical challenges and internal action mechanism of biomass injection. It clarified that alkali metals including potassium and sodium in biomass tended to undergo gasification migration and enrichment circulation in the high-temperature blast furnace system, which further destroyed the microstructure of coke and aggravated the deterioration of coke metallurgical properties. Meanwhile, this paper indicated that the dense three-dimensional network structure formed by biomass components was the key cause of its poor grindability. Aiming at the above technical bottlenecks, this paper systematically summarized the process characteristics and application limitations of multiple upgrading methods including ultrasonic cavitation dealkalization, baking pretreatment, steam explosion and hydrothermal carbonization. A novel collaborative treatment technology of dealkalization and grinding aid was proposed. Depending on green and recyclable additives, the technology realized the deep removal of alkali metals and synchronous improvement of grindability in a single step. Experimental results show that the proposed technology can control the total alkali metal content of biomass within the standard range for blast furnace injection and significantly optimize particle size indicators, and has obvious cost advantages compared with traditional processes. The research confirms that single technical optimization or multi-process coupling can make various performance indicators of biomass meet the technical requirements of blast furnace injection. The processed biomass has great application potential for large-scale pulverized coal substitution and can provide effective support for the application of biomass in blast furnaces.

     

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