Deoxidation and Inclusion Control in Special Steel Refining
XU Kuang-di1,XIAO Li-jun2
1. Chinese Academy of Engineering, Beijing 100088, China 2. National Engineering Research Center of Continuous Casting Technology of CISRI, Beijing 100081, China
Abstract:Special steel is a general designation of certain types of steel with higher cleanness upgraded gradually by steel factories with promotion of process and equipment step by step according to the customer demands on product quality. The total oxygen content in steel is extremely important for its cleanness, the requirements of total oxygen for different steel is different. In the deoxidation refining process, the reactions will take place among the deoxidation elements, dissolved oxygen in the steel, molten steel, slag, inclusions, and refractory and evolve into balance. These reactions have an important impact on the quantity, composition and morphology of inclusions in the steel. So we make comparison of the deoxidation ability with different deoxidation elements by thermodynamic calculation. The deoxidation mechanism and the control of inclusions during the refining process of typical steels (bearing steel, spring steel, cord steel, electrical steel, free cutting steel etc.) were also introduced. The mechanism of interaction among different deoxidation elements, molten steel, slag and refractory was analyzed and discussed.
收稿日期: 2012-06-07
出版日期: 2012-10-30
引用本文:
徐匡迪,肖丽俊. 特殊钢精炼中的脱氧及夹杂物控制[J]. 钢铁, 2012, 47(10): 1-13.
XU Kuang-di1,XIAO Li-jun2. Deoxidation and Inclusion Control in Special Steel Refining. Iron and Steel, 2012, 47(10): 1-13.
B.-H.Yoon, K.-H.Heo, J.-S.Kim, H.-S.Sohn. Improvement of Steel Cleanliness by Controlling Slag Composition. Ironmaking and steelmaking,2002,29(3):215-218
[10]
B.-H.Yoon, K.-H.Heo, J.-S.Kim, H.-S.Sohn. Improvement of Steel Cleanliness by Controlling Slag Composition. Ironmaking and steelmaking,2002,29(3):215-218
S. Maeda, T. Soejima, T. Saito, H. Matsumoto, H. Fujimoto, T. Mimura. Shape Control of Inclusions in Wire Rods for High Tensile Tire Cord by Refining with Synthetic Slag.1989 Steelmaking conference proceedings, 379-385
[12]
S. Maeda, T. Soejima, T. Saito, H. Matsumoto, H. Fujimoto, T. Mimura. Shape Control of Inclusions in Wire Rods for High Tensile Tire Cord by Refining with Synthetic Slag.1989 Steelmaking conference proceedings, 379-385
[13]
Jun Kawahara,Koji Tanabe, Toshio Banno, Masashi Yoshida.Advance of Valve Spring Steel.Wire Journal International.1992,(10):55-61
[13]
Jun Kawahara,Koji Tanabe, Toshio Banno, Masashi Yoshida.Advance of Valve Spring Steel.Wire Journal International.1992,(10):55-61
Takahiro Kushida, Yoshihiko Higuchi, Mitshiro Numata. Advanced Technologies of High Strength Linepipe for Sour Service. The Sumitomo Search,1996,58,(5):24-31
[16]
Takahiro Kushida, Yoshihiko Higuchi, Mitshiro Numata. Advanced Technologies of High Strength Linepipe for Sour Service. The Sumitomo Search,1996,58,(5):24-31
[17]
徐匡迪. 油、气管线用钢的性能要求与工艺技术进展.上海金属. 1986,8(4):1-11
[17]
徐匡迪. 油、气管线用钢的性能要求与工艺技术进展.上海金属. 1986,8(4):1-11
[18]
蒋育翔.X80管线钢夹杂物控制工艺的研究.特殊钢.2011,32(1):36-39
[18]
蒋育翔.X80管线钢夹杂物控制工艺的研究.特殊钢.2011,32(1):36-39
[19]
Yo-ichi,Seikoh Nara,Yoshiei Kato, Mamoru Suda. Shape Control of Alumina Inclusions by Double Calcium Addition Treatment. Tetsu-to-Hagané, 2007, 93(5):15-21
[19]
Yo-ichi,Seikoh Nara,Yoshiei Kato, Mamoru Suda. Shape Control of Alumina Inclusions by Double Calcium Addition Treatment. Tetsu-to-Hagané, 2007, 93(5):15-21
[20]
Yasuhiro Ehara, Seiji Yokoyama,Masahiro Kawakami. Formation Mechanism of Inclusions Containing MgO?Al2O3 Spinel in Type 304 Stainless Steel. Tetsu-to-Hagané, 2007, 93(3):8-14
[20]
Yasuhiro Ehara, Seiji Yokoyama,Masahiro Kawakami. Formation Mechanism of Inclusions Containing MgO?Al2O3 Spinel in Type 304 Stainless Steel. Tetsu-to-Hagané, 2007, 93(3):8-14
[21]
Jong wan KIM, Sun koo KIM, Dong sik KIM. Formation Mechanism of Type 304 Stainless Steel Ca-Si-Al-Mg-Ti-O Inclusions In Type 304 Stainless Steel. ISIJ International, 1996, 36, Supplement: S140-143
[21]
Jong wan KIM, Sun koo KIM, Dong sik KIM. Formation Mechanism of Type 304 Stainless Steel Ca-Si-Al-Mg-Ti-O Inclusions In Type 304 Stainless Steel. ISIJ International, 1996, 36, Supplement: S140-143
Y. Kurosaki, M. Shiozaki, K. Higashine, M. Sumimoto. Effect of Oxide shape on Magnetic Properties of Semiprocessed Nonoriented Electrical Steel Sheets. ISIJ International, 1999, 39(6):607-613
[27]
袁武华,王峰. 国内外易切削钢的研究现状和前景. 钢铁研究,2008,36(5):56-62
[26]
Y. Kurosaki, M. Shiozaki, K. Higashine, M. Sumimoto. Effect of Oxide shape on Magnetic Properties of Semiprocessed Nonoriented Electrical Steel Sheets. ISIJ International, 1999, 39(6):607-613
H. Todoroki, Y. Kanbe, K. Mizuno. Technology to Control Inclusions in Stainless Steels and High Ni Alloys. CAMP-ISIJ, 2003, 16: 844
[30]
H. Todoroki, Y. Kanbe, K. Mizuno. Technology to Control Inclusions in Stainless Steels and High Ni Alloys. CAMP-ISIJ, 2003, 16: 844
[31]
T. Nishi, K. Shimme. Formation of Spinel Inclusions in Molten Steel under Al Deoxidation with Slags. Tetsu-to-Hagané, 1998, 84(12):837-843
[31]
T. Nishi, K. Shimme. Formation of Spinel Inclusions in Molten Steel under Al Deoxidation with Slags. Tetsu-to-Hagané, 1998, 84(12):837-843
[32]
H. Todoroki, K. Mizuno. Variation of Inclusion Composition in 304 Stainless Steel Deoxidized with Aluminum. ISS Transaction, Iron Steelmaker, 2003,30:60
[32]
H. Todoroki, K. Mizuno. Variation of Inclusion Composition in 304 Stainless Steel Deoxidized with Aluminum. ISS Transaction, Iron Steelmaker, 2003,30:60
[33]
戴文斌,于景坤. 纯净钢冶炼用耐火材料. 材料与冶金学报. 2003, 2(1):3-9
[33]
戴文斌,于景坤. 纯净钢冶炼用耐火材料. 材料与冶金学报. 2003, 2(1):3-9
[34]
Yoshiyasu Shirota. Development of Production Process of Highly Clean Steel. CAMP-ISIJ. 1991, 4:1214-1217
[34]
Yoshiyasu Shirota. Development of Production Process of Highly Clean Steel. CAMP-ISIJ. 1991, 4:1214-1217
[35]
Issey Ibuki. Technology to Reduce Nonmetallic Inclusions for Clean Steel. CAMP-ISIJ. 1991, 4:1210-1213
[35]
Issey Ibuki. Technology to Reduce Nonmetallic Inclusions for Clean Steel. CAMP-ISIJ. 1991, 4:1210-1213
[36]
Goro Yuasa, Saburo Sugiura, Michihiko Fujine, Jun-Ichi Tsubokura. Effect of Refrctory on Deoxidation in Molten Steel. Transactions ISIJ, 1983,23:B-289
[36]
Goro Yuasa, Saburo Sugiura, Michihiko Fujine, Jun-Ichi Tsubokura. Effect of Refrctory on Deoxidation in Molten Steel. Transactions ISIJ, 1983,23:B-289