Castability improvement of high Ti-bearing welding wire steel
DENG Xu-yan1,2, MA Jian-chao1,ZHAO Wei-jie1
1. Institute of Research of Iron and Steel of Jiangsu Shasteel, Zhangjiagang 215625, Jiangsu, China 2. Dalipal Pipe Group Co., Ltd., Cangzhou 061000, Hebei, China
Abstract:Severe SEN (Submerged Entry Nozzle) clogging issue occurred in the continuous casting process of high Ti-bearing welding wire steel. The chemical composition of clogs was characterized using SEM/EDS. The results indicate that the major constituent phases are [TiOx] and solidified steel. The morphology and chemical composition of inclusions in liquid steel were analyzed by SEM/EDS. The results show the inclusion types at LF end are [MnO-Al2O3-SiO2-TiOx], [MgO-Al2O3-TiOx] and [TiOx]. The Ti-bearing inclusions with high melting point in liquid steel are the dominant reason to SEN clogging. Al-Ti-O equilibrium in liquid steel and steel-slag equilibrium were calculated by thermodynamic method. The results show oxygen is preferred to combine with Ti to form Ti2O3 when [w([Al])/w([Ti])<0.15], otherwise, oxygen is preferred to combine with Al; the titanium would not be oxidized by slag when [w((FeO))][<]0.05%, [w((SiO2))][<]15% in ladle slag. TiOx inclusion content in liquid steel is reduced from 0.002 4% to below 0.001% after the process parameters and operation are optimized; hence, the castability of liquid steel is improved significantly.
收稿日期: 2014-02-10
出版日期: 2015-02-02
引用本文:
邓叙燕,马建超,赵伟杰. 高钛焊丝用钢的钢液可浇性改善[J]. 钢铁, 2015, 50(2): 32-37.
DENG Xu-yan,, MA Jian-chao,ZHAO Wei-jie. Castability improvement of high Ti-bearing welding wire steel. Iron and Steel, 2015, 50(2): 32-37.