Prediction of composition distribution of non-metallic inclusions in a billet
ZHANG Yue-xin1, ZHANG Li-feng2, WANG Ju-jin1, NIU Kai-jun1, WANG Ya-dong1
1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei, China
Abstract:In order to study the spatial distribution of non-metallic inclusions in continuous casting billet, the variation of the average composition of inclusions in a cord steel billet from the loose side to the fixed side was analyzed. With the increase of the distance from the surface layer of the billet, the SiO2 content ascended significantly from 53% to about 75% firstly, and then declined to 60%. While the change of MnO content in inclusions declined to 12.59% firstly, and then ascended to 27.87%. The contents of CaO and Al2O3 inclusions changed little. An integrated model coupled with heat transfer, solidification, thermodynamic transformation of inclusion composition, and diffusion of dissolved elements in steel was established to predict the composition distribution of inclusions in the continuous casting billet. The calculated variation trend of oxide inclusion composition was consistent with the experimental one, which verified the accuracy of the model. Meanwhile, the evolution of inclusions in continuous casting billets of different total aluminum, total calcium, and total oxygen content was studied by using the model. The content of total aluminum had the greatest influence on the composition distribution of inclusions. When mass pertent of total aluminum increased from 0.000 1% to 0.001 0%, mass percent of SiO2 decreased from 57%-64% to 34%-39%; mass percent of Al2O3 increased from 8%-10% to 37%-41%; the content of MnO changed little; and mass percent of CaO decreased from 13%-17% to 8%-10%.
张月鑫, 张立峰, 王举金, 牛凯军, 王亚栋. 连铸坯全断面非金属夹杂物成分分布的预报[J]. 钢铁, 2021, 56(10): 74-82.
ZHANG Yue-xin, ZHANG Li-feng, WANG Ju-jin, NIU Kai-jun, WANG Ya-dong. Prediction of composition distribution of non-metallic inclusions in a billet[J]. Iron and Steel, 2021, 56(10): 74-82.
[1] 张立峰. 钢中非金属夹杂物:工业实践[M]. 北京: 冶金工业出版社, 2019.(ZHANG Li-feng. Non-metallic Inclusions in Steels: Industrial Practice[M]. Beijing: Metallurgical Industry Press, 2019.) [2] 张立峰. 钢中非金属夹杂物[M]. 北京: 冶金工业出版社, 2019.(ZHANG Li-feng. Non-metallic Inclusions in Steels: Fundamentals[M]. Beijing: Metallurgical Industry Press,2019.) [3] 朱殷翔. 帘线钢中夹杂物的控制[D].北京:北京科技大学,2009.(ZHU Yin-xiang. Control of Inclusions in Cord Steels[D].Beijing: University of Science and Technology Beijing, 2009.) [4] 王国栋, 吕亚伟. 82B硬线钢夹杂物控制研究与轧制工艺优化[J].中国冶金, 2012, 22(3): 15.(WANG Guo-dong, LÜ Ya-wei. Investigation of inclusions controlling and optimization of rolling process with high-carbon wire rod[J]. China Metallurgy, 2012, 22(3): 15.) [5] 李西德, 邓深, 杨跃标, 等. SWDH82B硬线钢CaO-Al2O3-SiO2系夹杂物塑性化控制的生产实践[J]. 中国冶金, 2018, 28(2): 61.(LI Xi-de, DENG Shen, YANG Yue-biao, et al. Productive practice of plastic deformation control of CaO-Al2O3-SiO2 inclusions in SWDH82B wire steel[J]. China Metallurgy, 2018, 28(2): 61.) [6] 王立峰, 卓晓军, 张炯明, 等. 冶金过程中帘线钢夹杂物成分控制[J]. 北京科技大学学报, 2003, 25(4): 308.(WANG Li-feng, ZHUO Xiao-jun, ZHANG Jiong-ming, et al. Control of inclusion composition of cord steel in metallurgical process[J]. Journal of University of Science and Technology Beijing, 2003, 25(4): 308.) [7] 汤伟, 杨俊, 刘青, 等. 高品质弹簧钢精炼过程氧化物夹杂的控制[J]. 中国冶金, 2020, 30(5): 17.(TANG Wei, YANG Jun, LIU Qing, et al. Control of oxide inclusions in high quality spring steel during refining process[J]. China Metallurgy, 2020, 30(5): 17.) [8] JIA Y N, ZHU L G, ZHANG C J, et al. Mass transfer behaviour of Mg in low carbon aluminium killed steel during LF refining[J]. Ironmaking and Steelmaking, 2016, 44(10): 796. [9] 音正元, 张立峰, 李超, 等. Q345D钢中含钙类夹杂物的演变和生成机理分析[J].钢铁,2020, 55(11): 47.(YIN Zheng-yuan, ZHANG Li-feng, LI Chao, et al. Analysis of evolution and formation mechanism of calcium-containing inclusions of Q345D steel[J]. Iron and Steel, 2020, 55(11): 47.) [10] 储焰平, 谌智勇, 刘南, 等. U75V重轨钢生产过程中非金属夹杂物的行为演变[J].中国冶金, 2018, 28(s1): 83.(CHU Yan-ping, CHEN Zhi-yong, LIU Nan, et al. Behavior evolution of non-metallic inclusions during production of U75V heavy rail steel[J]. China Metallurgy, 2018, 28(s1): 83.) [11] Itoh H, Fujii K, Nagasaka T, et al. Gibbs free energy and conditions of spinel (MgO·Al2O3) formation in liquid steel[J]. Steel Research International, 2003, 74(2): 86. [12] 程林, 杨文, 李树森, 等. “BOF→LF→RH→钙处理→CC”工艺生产管线钢过程夹杂物演变[J]. 炼钢, 2019, 35(6): 60.(CHENG Lin, YANG Wen, LI Shu-sen, et al. Evolution of inclusions in pipeline steel producted by the route of BOF-LF-RH-Ca treatment-CC[J]. Steelmaking, 2019, 35(6):60.) [13] 许国方, 张雪良, 杨树峰, 等. 20CrMnTi齿轮钢冶炼全流程的夹杂物分析[J]. 中国冶金, 2020, 30(11): 23.(XU Guo-fang, ZHANG Xue-liang, YANG Shu-feng, et al. Inclusion characterization in whole smelting process of 20CrMnTi gear steel[J]. China Metallurgy, 2020, 30(11): 23.) [14] Goto H, Miyazawa K, Yamaguchi K, et al. Effect of cooling rate on oxide precipitation during solidification of low carbon steels[J]. ISIJ International, 1994, 34(5): 414. [15] 成功, 蔡常青, 许英华, 等. SWRCH22A冷镦钢凝固冷却过程中非金属夹杂物的变化[J]. 中国冶金, 2018, 28(s1): 90.(CHENG Gong, CAI Chang-qing, XU Ying-hua, et al. Transformation of non-metallic inclusions in SWRCH22A cold heading steels during cooling and solidfication[J]. China Metallurgy, 2018, 28(s1): 90.) [16] ZHANG Y X, ZHANG L F, CHU Y P, et al. Transformation of inclusions in a complicated-deoxidized heavy rail steels during heating[J]. Steel Research International, 2020, 91(9): 2000120. [17] 张国锋, 季莎, 张立峰, 等. 20CrMnTiH齿轮钢凝固和冷却过程中非金属夹杂物的转变研究[J]. 炼钢, 2020, 36(3): 32.(ZHANG Guo-feng, JI Sha, ZHANG Li-feng, et al. Study on transformation of non-metallic inclusions in 20CrMnTiH gear steel during solidification and cooling process[J]. Steelmaking, 2020, 36(3): 32.) [18] 王祎, 张立峰, 杨文, 等. Q345钢液凝固及铸坯冷却过程中非金属夹杂物的组成演变[J]. 炼钢, 2020, 36(2): 29.(WANG Yi, ZHANG Li-feng, YANG Wen, et al. Evolution of non-metallic inclusion composition during cooling and solidification process of Q345 Steel[J]. Steelmaking, 2020, 36(2): 29.) [19] 辛广胜, 储焰平, 任英, 等. 重轨钢凝固和冷却过程中非金属夹杂物生成热力学及工业实践[J]. 炼钢, 2020, 36(4): 39.(XIN Guang-sheng, CHU Yan-ping, REN Ying, et al. Thermodynamics and industrial practice of non-metallic inclusions of heavyrail steel during solidification and cooling[J]. Steelmaking, 2020, 36(4): 39.) [20] 王海涛, 许中波, 王福明. 帘线钢凝固过程中夹杂物析出[J]. 北京科技大学学报, 2007, 29(9): 884.(WANG Hai-tao, XU Zhong-bo, WANG Fu-ming. Inclusion precipitation during solidification of cord steels[J]. Journal of University of Science and Technology Beijing, 2007, 29(9): 884.) [21] 牛凯军, 杨文, 张立峰, 等. 帘线钢凝固过程夹杂物生成热力学及工业实践[J]. 钢铁, 2020, 55(6): 61.(NIU Kai-jun, YANG Wen, ZHANG Li-feng, et al. Thermodynamics and industrial practice of formation of inclusions during solidification of tire cord steels[J]. Iron and Steel, 2020, 55(6): 61.) [22] CHEN W, REN Y, ZHANG L F. Large eddy simulation on the fluid flow, solidification and entrapment of inclusions in the steel along the full continuous casting slab strand[J]. JOM, 2018, 70(12): 2968. [23] ZHANG L F, WANG Y F. Modeling the entrapment of nonmetallic inclusions in steel continuous-casting billets[J]. JOM, 2012, 64(9): 1063. [24] REN Q, ZHANG Y X, REN Y, et al. Prediction of spatial distribution of the composition of inclusions on the entire cross section of a linepipe steel continuous casting slab[J]. Journal of Materials Science and Technology, 2020, 61: 147. [25] REN Q, ZHANG Y X, ZHANG L F, et al. Prediction on the spatial distribution of the composition of inclusions in a heavy rail steel continuous casting bloom[J]. Journal of Materials Research and Technology, 2020, 9(3): 5648. [26] WANG J J, ZHANG L F, ZHANG Y X, et al. Prediction of spatial composition distribution of inclusions in the continuous casting bloom of a bearing steel under unsteady casting[J]. ISIJ International, 2021, 61(3): 824. [27] Won Y, Thomas B G. Simple microsegregation model for steel solidification[J]. Metallurgical and Materials Transactions A, 2001, 32(7): 1755. [28] Ueshima Y, Mizoguchi S, Matsumiya T, et al. Analysis of solute distribution in dendrites of carbon steel with δ/γ transformation during solidification[J]. Metallurgical and Materials Transactions B, 1986, 17(4): 845.