Influence of hydrogen-rich on softening and melting property of blast furnace burden with vanadium and titanium
QIE Ya-na1, JIN Ya-tao2, KANG Yuan2, LI Li-fen2, WANG Yi-fan1, WANG Xin-dong3
1. College of Metallurgy and Energy, North China University of Technology,Tangshan 063009, Hebei, China; 2. Chengde Branch, HBIS Co., Ltd., Chengde 067002, Hebei, China; 3. HBIS Group, Shijiazhuang 050000, Hebei, China
Abstract:Hydrogen-rich metallurgy in blast furnace(BF) is an important way to reduce energy consumption and carbon emission.The influence of hydrogen-rich reduction on the process of softening and melt dripping of vanadium titanium ore was studied, and the change of reduction degree and amount of primary of vanadium-titaniumd burden during the process was analyzed by the process interruption method. The results showed that,the softening and shrinkage behavior of vanadium titanium ore is closely related to its reduction process. With the acceleration of hydrogen-rich reduction rate, the reduction expansion of vanadium-titanite at 500-900 ℃ is intensified. With the increase of FeO, the shrinkage deformation rate of vanadium-titanium ore increases below 1 100 ℃. The reduction rate of H2 is 8 times of that of CO at 1 100 ℃. The gradually thickening iron shell and the increase of the melting point of the primary slag lead to the increase of the melting and droping temperature. When the hydrogen enrichment rate is 10%, the amount of primary smelting slag with vanadium titanium ore is reduced by half, from nearly 900 kg/t to about 460 kg/t, it is close to the final slag amount, which will reduce the gas resistance loss and greatly improve the permeability of cohensive zone of BF. Hydrogen-rich reduction reduces the interaction and coupling reaction between FeO and ilmenite FeTiO3 and ilmenite SPAR Fe2TiO4 at high temperature, which promotes the separation of melting slag and metal iron in cohensive zone, and effectively reduces the flooding phenomenon of melt in the bosh.The hydrogen-rich operation of BF with vanadium titanium ore will make the cohensive zone move down and the thickness thin, especially the melting zone with the worst permeability become narrowed. This indicates that hydrogen-rich reduction of BF with vanadium titanite ore not only reduces the carbon consumption and CO2emission, but also improves the state of cohensive zone and promotes the anterograde high yield of BF.
郄亚娜, 靳亚涛, 康媛, 李丽芬, 王艺帆, 王新东. 高炉富氢对钒钛矿软熔滴落性能的影响[J]. 钢铁, 2023, 58(5): 31-38.
QIE Ya-na, JIN Ya-tao, KANG Yuan, LI Li-fen, WANG Yi-fan, WANG Xin-dong. Influence of hydrogen-rich on softening and melting property of blast furnace burden with vanadium and titanium[J]. Iron and Steel, 2023, 58(5): 31-38.
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