Abstract:To improve the hydrogen permeation resistance of 18CrNiMo7-6 steel,it was strengthened by ultrasonic surface rolling process (USRP) under different static pressure,the hardness of the sample in the cross section and the residual stress of the surface layer of the material were measured,and the effect of USRP on the surface integrity and hydrogen permeation property of 18CrNiMo7-6 steel was analyzed. To further explore the influence of residual stress generated by USRP on the hydrogen permeation,URSP and stress-coupled hydrogen diffusion process was simulated in ABAQUS finite element software. The results show that with the increase of static pressure,the surface microhardness and surface compressive residual stress obtained by USRP gradually increase,and the hydrogen permeability decreases; When the static pressure of USRP is 100,200,300,400 N,the surface microhardness increases by 14%、15%、19%、27% compared with the sample without USRP,the surface compressive residual stress increases by 513%、943%、1 013%、1 063% and the hydrogen permeation parameter decreases by 30%,32%,36%,55% compared with the sample without USRP. The numerical simulation results show that USRP causes compressive residual stress with gradient distribution,and the influence depth and maximum value of compressive residual stress are positively correlated with static pressure; Hydrogen diffuses in the material driven by the concentration gradient. The hydrogen mass percent in the area treated by USRP decreases rapidly along the depth direction,and the largest decline was appeared at the depth of 100 μm from the top surface. The distribution trend of hydrogen mass percent is the same with that of hydrostatic stress,the hydrogen mass percent is low where hydrostatic compressive stress exists,and the hydrogen mass percent is high where hydrostatic tensile stress exists. The compressive residual stress produced by USRP can inhibit hydrogen permeation.
王刚, 顾飞翔, 秦瑾鸿, 李俊昊, 彭振龙. 超声滚压对18CrNiMo7-6合金钢抗氢渗透性能的影响[J]. 钢铁, 2023, 58(7): 125-132.
WANG Gang, GU Feixiang, QIN Jinhong, LI Junhao, PENG Zhenlong. Effect of ultrasonic surface rolling process on hydrogen permeation resistance of 18CrNiMo7-6 steel[J]. Iron and Steel, 2023, 58(7): 125-132.
[1] 王刚,路留成,张悦,等. 18CrNiMo7-6合金钢表面变质层循环特性[J]. 钢铁,2022,57(9):156. (WANG G,LU L C,ZHANG Y,et al. Cyclic characteristics of surface-modified layers of 18CrNiMo7-6 alloy steel[J]. Iron and Steel,2022,57(9):156.) [2] SPRINGER P,PRAHL U. Characterisation of mechanical behavior of 18CrNiMo7-6 steel with and without Nb under warm forging conditions through processing maps analysis[J]. Journal of Materials Processing Technology,2016,237:216. [3] PENG G,ANDREJ T,JOHN N,et al. Hydrogen embrittlement mechanisms in advanced high strength steel[J]. Acta Materialia,2022,223:117488. [4] AKIYAMA E. Evaluation of delayed fracture property of high strength bolt steels[J]. ISIJ International,2012,52(2):307. [5] TARUI T,YAMASAKI S. Evaluation method of delayed fracture property and overcoming techniques of delayed fracture of high strength steels[J]. Tetsu-to-Hagane,2002,88(10):612. [6] HINO M,MUKAI S,SHIMADA T,et al. Effect of baking on hydrogen embrittlement for high strength steel treated with various zinc based electroplating from a sulfate bath[J]. Journal of the Japan Institute of Metals and Materials,2020,84(3):87. [7] LI H, VENEZUELA J, ZHOU Q, et al. Effect of shearing prestrain on the hydrogen embrittlement of 1 180 MPa grade martensitic advanced high-strength steel[J]. Corrosion Science,2022,199:110170. [8] 刘振宝,梁剑雄,杨哲,等. 高强度不锈钢应用及研究进展[J]. 中国冶金,2022,32(6):42. (LIU Z B,LIANG J X,YANG Z,et al. Progress of application and research on high strength stainless steel[J]. China Metallurgy,2022,32(6):42.) [9] 赵晓丽,张永健,惠卫军,等. 不同轧制及退火处理0.1C-5Mn中锰钢的氢脆敏感性[J]. 钢铁,2019,54(11):69. (ZHAO X L,ZHANG Y J,HUI W J,et al. Hydrogen embrittlement of intercritically annealed medium-Mn steel (0.1C-5Mn) under different rolling conditions[J]. Iron and Steel,2019,54(11):69.) [10] 谌康,徐乐,时捷,等. 新型超高强度低氢脆敏感性扭杆弹簧用钢[J]. 钢铁,2017,52(5):94. (CHEN K,XU L,SHI J,et al. A new torsion bar spring steel with ultra-high strength and low hydrogen embrittlement sensitivity[J]. Iron and Steel,2017,52(5):94.) [11] AGYENIM-BOATENG E,HUANG S,SHENG J,et al. Influence of laser peening on the hydrogen embrittlement resistance of 316L stainless steel[J]. Surface and Coatings Technology,2017,328:44. [12] WANG Y,XIE H,ZHOU Z,et al. Effect of shot peening coverage on hydrogen embrittlement of a ferrite-pearlite steel[J]. International Journal of Hydrogen Energy,2020,45(11):7169. [13] AN T,LI S,QU J,et al. Effects of shot peening on tensile properties and fatigue behavior of X80 pipeline steel in hydrogen environment[J]. International Journal of Fatigue,2019,129:105235. [14] HUANG S,LI H,ZHANG H,et al. Experimental study and finite element simulation of hydrogen permeation resistance of Ti-6Al-4V alloy strengthened by laser peening[J]. Surface and Coatings Technology,2020,400:126217. [15] LI X,ZHANG J,WANG Y,et al. The dual role of shot peening in hydrogen-assisted cracking of PSB1080 high strength steel[J]. Materials and Design,2016,110:602. [16] 昝娜,丁桦,骆小鹏,等. 晶粒尺寸对高锰奥氏体TWIP钢氢脆行为的影响[J]. 中国冶金,2016,26(1):23. (ZAN N,DING H,LUO X P,et al. Effect of grain size on hydrogen embrittlement of high Mn austenitic TWIP steel[J]. China Metallurgy,2016,26(1):23.) [17] ZHOU M, XU Y, LIU Y, et al. Microstructures and mechanical properties of Mg-15Gd-1Zn-0.4Zr alloys treated by ultrasonic surface rolling process[J]. Materials Science and Engineering A,2021,828:141881. [18] 巩立超,潘永智,刘彦杰,等. 超声滚压轴承套圈表面强化的研究综述[J]. 表面技术,2022,51(8):203. (GONG L C,PAN Y Z,LIU Y J,et al. Surface strengthening of ultrasonic rolling bearing rings[J]. Surface Technology,2022,51(8):203.) [19] CHENG M,ZHANG D,CHEN H,et al. Development of ultrasonic thread root rolling technology for prolonging the fatigue performance of high strength thread[J]. Journal of Materials Processing Technology,2014,214(11):2395. [20] ZHANG Y,HUANG L,LU F,et al. Effects of ultrasonic surface rolling on fretting wear behaviors of a novel 25CrNi2MoV steel[J]. Materials Letters,2021,284:128955. [21] 谢学涛,何柏林,金辉,等. 超声冲击对P355 NL1钢焊接接头超高周疲劳性能影响[J]. 钢铁,2017,52(11):59. (XIE X T,HE B L,JIN H,et al. Effects of ultrasonic impact treatment on very high cycle fatigue properties of P355 NL1 steel welded joint [J]. Iron and Steel,2017,52(11):59.) [22] JOHNSON G R,COOK W H. A constitutive model and data for metals subjected to large strains,high strain rates and high temperatures[J]. Engineering Fracture Mechanics,1983,21:541. [23] 张天增. 超声滚压装置及其工艺试验的研究[D]. 郑州:郑州大学,2019. (ZHANG T Z. Research on Ultrasonic Rolling Device and Its Processing Experiment[D]. Zhengzhou:Zhengzhou University,2019.) [24] 杜天海. 高压临氢管线环焊接头的氢渗透动力学研究[D]. 青岛:中国石油大学(华东),2017. (DU T H. Study on Hydrogen Permeation Dynamics in Girth Joint of Pipeline Steel under High Pressure Hydrogen Gas Environment[D]. Qingdao:China University of Petroleum(East China),2017.) [25] 王婷,王东坡,刘刚,等. 40Cr超声表面滚压加工纳米化[J]. 机械工程学报,2009,45(5):177. (WANG T,WANG D P,LIU G,et al. 40Cr nano-crystallization by ultrasonic surface rolling extrusion processing[J]. Journal of Mechanical Engineering,2009,45(5):177.) [26] 龙琼,余静喜,李保军,等. Ce合金化及喷丸对Q235钢组织和力学性能的影响[J]. 上海金属,2020,42(4):26. (LONG Q,YU J X,LI B J,et al. Effect of Ce alloying and shot peening on microstructure and mechanical properties of Q235 steel[J]. Shanghai Metals,2020,42(4):26.) [27] LEE H,MALL S,ALLEN W Y. Fretting fatigue behavior of shot-peened Ti-6Al-4V under seawater environment[J]. Materials Science and Engineering A,2006,420(1):72. [28] TAKAKUWA O,NISHIKAWA M,SOYAMA H. Numerical simulation of the effects of residual stress on the concentration of hydrogen around a crack tip[J]. Surface and Coatings Technology,2012,206(11):2892. [29] TORIBIO J,KHARIN V,LORENZO M,et al. Role of drawing-induced residual stresses and strains in the hydrogen embrittlement susceptibility of prestressing steels[J]. Corrosion Science,2011,53(10):3346. [30] GO O,TOSHIMITSU Y A,TOSHIHITO O,et al. Hydrogen concentration behavior of y-grooved weld joint based on a coupled analysis of heat transfer-thermal stress-hydrogen diffusion[J]. Advanced Materials Letters,2018,9(10):677.