Effect of B2O3-Na2O slag modifier on desulfurization slag performance of hot metal containing vanadium and titanium
YANG Bi-wen1, WANG Hai-bei1, ZHENG Chao-zhen1, CHEN Liang2, HU Yi-hang3
1. Research and Design Institute of Metallurgical, BGRIMM Technology Group, Beijing 100160, China; 2. State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Pangang Group Research Institute Co., Ltd., Panzhihua 617000, Sichuan, China; 3. School of Engineering, Peking University, Beijing 100871, China
Abstract:In order to solve the problems of thick of slag, large of iron loss, and much of resulfurization in the slagging-off process after pre-desulfurization of hot metal containing vanadium and titanium, the effect of B2O3-Na2O slag modifier on resulfurization, melting point, and viscosity of the desulfurization slag was investigated by using FactSage thermodynamic software and combing with high-temperature experiments. The results showed that the melting point and viscosity of the desulfurization slag decreased significantly with the addition of B2O3 and Na2O. And the addition of CaO to the slag modifier helped to reduce resulfurization. The formula of slag modifier (45%-55% of CaO, 10%-12% of SiO2, 5%-8% of Al2O3, 15%-20% of B2O3, and 5%-10% of Na2O) to improve the performance of desulfurization slag was presented. It effectively reduced the melting point and viscosity of desulfurization slag and decreased the resulfurization, when the added amount of the slag modifier was 5%-10% of the desulfurization slag.
杨必文, 王海北, 郑朝振, 陈亮, 胡一航. B2O3-Na2O系调渣剂对钒钛铁水脱硫渣性能的影响[J]. 钢铁, 2021, 56(10): 91-98.
YANG Bi-wen, WANG Hai-bei, ZHENG Chao-zhen, CHEN Liang, HU Yi-hang. Effect of B2O3-Na2O slag modifier on desulfurization slag performance of hot metal containing vanadium and titanium[J]. Iron and Steel, 2021, 56(10): 91-98.
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