Abstract:In order to study the effect of B content on the microstructure and mechanical properties of FB2 steel,five groups of FB2 steels with different B contents were immersed and corroded for 90 s with Veller's reagent (1 g picric acid,5 mL hydrochloric acid and 100 mL anhydrous ethanol),and the morphology was observed and analyzed. Then,The M23C6 carbide in the matrix was observed and analyzed by SEM-EDS,and the size of precipitated phase was analyzed by Image-Pro Plus software. Then,the AG-XPLUS 100 kN universal testing machine produced by Shimadzu Manufacturing Institute of Japan was used to conduct room temperature tensile test and room temperature impact test on 5 groups of FB2 steel with different B content. Finally,the microstructure and mechanical properties of five groups of FB2 steels with different B contents were analyzed. The results show that the B element in FB2 steel can inhibit the growth coarsening of M23C6 type carbides,but B element is easy to form BN inclusions with N element. With the increase of B content,the average size of M23C6 carbide decreases,and the unit number and average size of BN inclusions show an increasing trend. The tensile properties of FB2 steel at room temperature increase first and then decrease with the increase of B content,and the tensile properties of FB2 steel reach the maximum at 0.010% B mass percent. When the mass percent of B increases from 0 to 0.010%,the tensile properties of FB2 steel increase at room temperature because the addition of B prevents the coarsening of M23C6 carbide,and thus improves the strength of FB2 steel. When the mass percent of B increases from 0.010% to 0.030%,the tensile property of FB2 steel decreases at room temperature because the BN inclusion formed by the combination of B element and N element causes stress concentration,and the large size BN inclusions induce the formation of holes,which reduces the properties of FB2 steel. The impact energy of FB2 steel decreases with the increase of B content,and plummets when the B mass percent is 0.020% and 0.030%,which is caused by the unit number of BN inclusions,the increase of average diameter,and the precipitation of large size BN and debris.
陶学儒, 耿鑫, 姜周华, 李扬, 彭雷朕. 硼元素对FB2钢组织和力学性能的影响[J]. 钢铁, 2022, 57(10): 158-169.
TAO Xue-ru, GENG Xin, JIANG Zhou-hua, LI Yang, PENG Lei-zhen. Effect of element B on microstructure and mechanical properties of FB2 steel[J]. Iron and Steel, 2022, 57(10): 158-169.
[1] Nan Z,Fridley D,Khanna N Z,et al. China's energy and emissions outlook to 2050:Perspectives from bottom-up energy end-use model[J]. Energy Policy,2013,53(2):51. [2] 刘正东,程世长,唐广波,等. 中国电站用钢技术现状和未来发展[J]. 钢铁,2011,46(3):1. (LIU Zheng-dong,CHENG Shi-chang,TANG Guang-bo,et al. The state-of-the-art of steel technology used for Chinese power plants and its future[J]. Iron and Steel,2011,46(3):1.) [3] Blaes N,Donth B, Bokelmann D. High chromium steel forgings for steam turbines at elevated temperatures[J]. Energy Materials,2007,2(4):207. [4] Chetal S C. Materials research and opportunities in thermal (coal-based) power sector including advanced ultra super critical power plants[J]. Proceedings of the Indian National Science Academy,2015,81(4):739. [5] Viswanathan R,Bakker W. Materials for ultrasupercritical coal power plants—Boiler materials:Part 1[J]. Journal of Materials Engineering and Performance,2001,10(1):96. [6] Weber V,Jardy A,Dussoubs B,et al. A comprehensive model of the electroslag remelting process:Description and validation[J]. Metallurgical and Materials Transactions B,2009,40(3):271. [7] Kern T U,Staubli M,Scarlin B. The European efforts in material development for 650 ℃ CUSC power plants-COST522[J]. Transactions of the Iron and Steel Institute of Japan,2002,42(12):1515. [8] Ghosh S. The role of tungsten in the coarsening behavior of M23C6,carbide in 9Cr-W steels at 600 ℃[J]. Journal of Materials Science,2010,45(7):1823. [9] ZHOU Xiao-ling,SHEN Yin-zhong,XU Zhi-qiang. Precipitate phases in an 11%Cr ferritic/martensitic steel with tempering and creep conditions[J]. Acta Metallurgica Sinica(English Letters),2015,28(1):48. [10] Abe F,Tabuchi M,Kondo M,et al. Suppression of type IV fracture in welded joints of advanced ferritic power plant steels-effect of boron and nitrogen[J]. Materials at High Temperatures,2006,23(3/4):145. [11] Abe F,Taneike M,Sawada K. Alloy design of creep resistant 9Cr steel using a dispersion of nano-sized carbonitrides[J]. International Journal of Pressure Vessels and Piping,2007,84(1/2):3. [12] Prat O,Garcia J,Rojas D,et al.The role of laves phase on microstructure evolution and creep strength of novel 9%Cr heat resistant steels[J].Intermetallics,2013,32:362. [13] Panait C G,Bendick W,Fuchsmann A,et al.Study of the microstructure of the Grade 91 steel after more than 100 000 h of creep exposure at 600 ℃ [J].International Journal of Pressure Vessels and Piping,2010,87(6):326. [14] Horiuchi T,Igarashi M,Abe F. Improved utilization of added B in 9Cr heat resistant steels containing W[J]. ISIJ International,2002,42(Suppl):S67. [15] Abe F. Effect of boron on microstructure and creep strength of advanced ferritic power plant steels[J]. Procedia Engineering,2011,10(4):94. [16] Abe F. Bainitic and martensitic creep-resistant steels[J]. Current Opinion in Solid State and Materials Science,2004,8(3/4):305. [17] Matsunaga T,Hongo H,Tabuchi M. Creep lifetime and microstructure evolution in boron-added 9Cr-1Mo heat-resistant steel[J]. Materials Science and Engineering A,2019,760(8):267. [18] XIAO X,YANG C,QIN X Z,et al. Effects of B and P on microstructure and mechanical properties of a superalloy used for 700 ℃ advanced ultra-supercritical steam turbine[J]. Raremetal Materials and Engineering,2017,46(4):7. [19] Abe F. Precipitate design for creep strengthening of 9% Cr tempered martensitic steel for ultra-supercritical power plants[J]. Science and Technology of Advanced Materials,2008,9(1):013002. [20] 田仲良,包汉生,何西扣,等. 700 ℃汽轮机转子用耐热合金的强化机理[J]. 钢铁研究学报,2015,27(9):1. (TIAN Zhong-liang,BAO Han-sheng,HE Xi-kou,et al. Strengthening mechanisms of heat resistant alloys used for steam turbine rotor working at 700 ℃[J]. Journal of Iron and Research,2015,27(9):1.) [21] CEN Q H,ZHANG H B,FU H G. Effect of heat treatment on structure and wear resistance of high chromium cast steel containing boron[J]. Journal of Iron and Steel Research,International,2014,21(5):532. [22] Abe F,Araki H,Noda T. The effect of tungsten on dislocation recovery and precipitation behavior of low-activation martensitic 9Cr steels[J]. Metallurgical Transactions A,1991,22(10):2225. [23] Kostka A,Tak K G,Hellmig R J,et al. On the contribution of carbides and micrograin boundaries to the creep strength of tempered martensite ferritic steels[J]. Acta Materialia,2007,55(2):539. [24] Armaki H G,Chen R,Maruyama K,et al. Creep behavior and degradation of subgrain structures pinnedby nanoscale precipitates in strengthen hanced 5 to 12% Cr ferritic steels[J]. Metallurgical and Materials Transactions A,2011,42(10):3084. [25] Taneike M,Sawada K,Abe F. Effect of carbon concentration on precipitation behavior of M23C6carbides and MX carbonitrides in martensitic 9Cr steel during heat treatment[J]. Metallurgical and Materials Transactions A,2004,35(4):1255. [26] LIU Xin-quan,YANG Gang,WU Xing-hui,et al. Effect of long-termaging at 620 ℃ on structure and mechanical properties of a new ferrite heat resistant steel 1Cr11Co3 W3MoVNbNB[J]. Special Steel,2010,31(5):67. [27] Panait C G,Bendick W,Fuchsmann A,et al. Study of the microstructure of the Grade 91 steel after more than 100 000 h of creep exposure at 600 ℃[J]. International Journal of Pressure Vessels and Piping,2010,87(6):326. [28] Albu M,Mayr P,Martin F M,et al. The influence of boron on the microstructure of a 9wt% Cr ferritic steel [J]. Materials at High Temperatures,2011,28(2):120. [29] Hald J,Korcakova L. Precipitate stability in creep resistant ferritic steels-experimental investigations and modelling[J]. ISIJ International,2003,43(3):420. [30] 汉姆弗莱斯 F J,唐廼泳. 位错与硬粒子的交互作用[J]. 材料科学与工程,1985(4):30. (Hamfries F J,TANG Nai-yong. Interactions between dislocations and hard particles[J]. Journal of Materials Science and Engineering,1985(4):30.) [31] Hayakawa H,Nakashima S,Kusumoto J,et al. Creep deformation characterization of heat resistant steel by stress change test [J]. International Journal of Pressure Vessels and Piping,2009,86(9):556. [32] Hawk J A,Jablonski P D,Cowen C J. Creep Resistant High Temperature Martensitic Steel:USA,9556503[P]. 2017-01-31. [33] Emad E K,Kentaro A,Koji S. Effects of nitrogen in 9Cr-3W-3Co ferritic heat resistant steels containing boron[J]. ISIJ International,2002,42(12):1468. [34] 崔忠圻. 金属学与热处理(铸造,焊接专业用)[M]. 北京:机械工业出版社,1989. (CUI Zhong-qi. Metallurgy and Heat Treatment (for Casting,Welding)[M]. Beijing:China Machine Press,1989.) [35] 王献钧. 舰船结构钢的夏比冲击韧性与断口形貌[J]. 材料开发与应用,1995,10(1):44. (WANG Xian-jun. Charpy impact toughness and fracture appearance of ship structural steels[J]. Development and Application of Materials,1995,10(1):44.) [36] 钟群鹏,赵子华. 断口学[M]. 北京:高等教育出版社,2005. (ZHONG Qun-peng,ZHAO Zi-hua. Fractography[M]. Beijing:Higher Education Press,2005)