Abstract:As a common micro-alloying element,Nb element is often used to refine the grain to improve strength and toughness of steel. However,the study on the quantitative relationship between Nb element and carbide mass percent and the reasonable ratio of Nb and C in stainless steel is not enough. The way Nb mass percent effect on the microstructure and carbides of 1Cr13 and 3Cr13 was observed and analyzed,a reasonable equation of C-Nb relation and the influence of these two elements on carbide mass percent of quantitative relationship have been obtained. Experiment results show that Nb elements can promote the precipitation of carbide and changing the composition of carbides (Nb element can be found in carbides). By the way,with the increase of Nb mass percent,the carbide in Cr13 series martensitic stainless steel increases exponentially. Finally,the mass percent of carbide and the mass percents of C and Nb in Cr13 series martensitic stainless steels has an exponential relationship. At the same time,the reasonable ratio of C-Nb relationship is linear.
金洋帆, 臧其玉, 张 拓, 杨弋涛. Cr13系铸造马氏体不锈钢铌和碳的合理配比关系[J]. 钢铁, 2019, 54(3): 87-95.
JIN Yang-fan, ZANG Qi-yu, ZHANG Tuo, YANG Yi-tao. Reasonable proportioning relationship between Nb and C of Cr13 series casting martensitic stainless steel. Iron and Steel, 2019, 54(3): 87-95.
Vignal V, Ringeval S, Thiebaut S, et al. Influence of the microstructure on the corrosion behaviour of low-carbon martensitic stainless steel after tempering treatment[J]. Corrosion Science, 2014, 85:42.
[1]
Vignal V, Ringeval S, Thiebaut S, et al. Influence of the microstructure on the corrosion behaviour of low-carbon martensitic stainless steel after tempering treatment[J]. Corrosion Science, 2014, 85:42.
[2]
张二红,张华龙.马氏体不锈钢发展现状与趋势[J].煤矿机械,2014,35(14):16.
[2]
张二红,张华龙.马氏体不锈钢发展现状与趋势[J].煤矿机械,2014,35(14):16.
(Zhang E H, Zhang H L. Martensitic Stainless Steel Development Status and Trends[J]. Coal Mine Machinery, 2014, 35(14):16.)
(Zhang E H, Zhang H L. Martensitic Stainless Steel Development Status and Trends[J]. Coal Mine Machinery, 2014, 35(14):16.)
[3]
Usama M A, Jeffrey R A. A review of micro-powder injection moulding as a microfabrication technique[J]. Journal of Micromechanics and Microengineering, 2011, 21:43001.
[3]
Usama M A, Jeffrey R A. A review of micro-powder injection moulding as a microfabrication technique[J]. Journal of Micromechanics and Microengineering, 2011, 21:43001.
[4]
El-Sharif M R, Watson A, Chisholm C U. The sustained deposition of thick coatings of chromium/nickel and chromium/nickel/iron alloys and their properties[J]. Transactions of the IMF, 1988, 66:34.
[4]
El-Sharif M R, Watson A, Chisholm C U. The sustained deposition of thick coatings of chromium/nickel and chromium/nickel/iron alloys and their properties[J]. Transactions of the IMF, 1988, 66:34.
[5]
Sanni O, Popoola A P I, Fayomi O S I. Enhanced corrosion resistance of stainless steel type 316 in sulphuric acid solution using eco-friendly waste product[J]. Results in Physics, 2018, 9:225.
[5]
Sanni O, Popoola A P I, Fayomi O S I. Enhanced corrosion resistance of stainless steel type 316 in sulphuric acid solution using eco-friendly waste product[J]. Results in Physics, 2018, 9:225.
[6]
Schoof E, Schneider D, Streichhan N, et al. Multiphase-field modeling of martensitic phase transformation in a dual-phase microstructure[J]. International Journal of Solids and Structures, 2018, 134:181.
[6]
Schoof E, Schneider D, Streichhan N, et al. Multiphase-field modeling of martensitic phase transformation in a dual-phase microstructure[J]. International Journal of Solids and Structures, 2018, 134:181.
[7]
Hamasaki H, Ohno T, Nakano T, et al. Modelling of cyclic plasticity and martensitic transformation for type 304 austenitic stainless steel[J]. International Journal of Mechanical Sciences, 2017, 000:1.
[7]
Hamasaki H, Ohno T, Nakano T, et al. Modelling of cyclic plasticity and martensitic transformation for type 304 austenitic stainless steel[J]. International Journal of Mechanical Sciences, 2017, 000:1.
[8]
Gualtieri T, Bandyopadhyay A. Additive manufacturing of compositionally gradient metal-ceramic structures: Stainless steel to vanadium carbide[J]. Materials and Design, 2018, 139:419.
[8]
Gualtieri T, Bandyopadhyay A. Additive manufacturing of compositionally gradient metal-ceramic structures: Stainless steel to vanadium carbide[J]. Materials and Design, 2018, 139:419.
[9]
Sahasrabudhe H, Harrison R, Carpenter C, et al. Stainless steel to titanium bimetallic structure using LENSTM[J]. Additive Manufacturing, 2015, 5:1.
[9]
Sahasrabudhe H, Harrison R, Carpenter C, et al. Stainless steel to titanium bimetallic structure using LENSTM[J]. Additive Manufacturing, 2015, 5:1.
[10]
Fujimura H, Tsuge S. Effect of Nb on strength and corrosion-resistance in low carbon martensitic stainless steel[J],CAMP-ISIJ, 1997, 10: 568.
[10]
Fujimura H, Tsuge S. Effect of Nb on strength and corrosion-resistance in low carbon martensitic stainless steel[J],CAMP-ISIJ, 1997, 10: 568.
[11]
Ma X P, Wang L J, Liu C M, et al. Role of Nb in low interstitial 13Cr super martensitic stainless steel[J]. Materials Science and Engineering A, 2011, 528:6872.
[11]
Ma X P, Wang L J, Liu C M, et al. Role of Nb in low interstitial 13Cr super martensitic stainless steel[J]. Materials Science and Engineering A, 2011, 528:6872.
[12]
Yuan J P, Li W. Antibacterial 316L Stainless Steel Containing Silver and Niobium[J]. Rare Metal Materials and Engineering, 2013, 42(10):2004.
[12]
Yuan J P, Li W. Antibacterial 316L Stainless Steel Containing Silver and Niobium[J]. Rare Metal Materials and Engineering, 2013, 42(10):2004.
[13]
Baghjari S H, Ghaini F M, Previtali B, et al. The effect of electrospark nickel interlayer thickness on the characteristics of Niobium to 410 stainless steel dissimilar laser welding[J]. Journal of Manufacturing Processes, 2017, 30:51.
[13]
Baghjari S H, Ghaini F M, Previtali B, et al. The effect of electrospark nickel interlayer thickness on the characteristics of Niobium to 410 stainless steel dissimilar laser welding[J]. Journal of Manufacturing Processes, 2017, 30:51.
[14]
Zhao Y T, Dong J H, Ma Y L, et al. Mechanical and Galvano-chemistry Property Variation within Dissimilar Metal Weld between 1Cr18Ni9Ti and 1Cr13 Stainless Steel[J]. Journal of Materials Science & Technology, 2010, 26(5):477.
[14]
Zhao Y T, Dong J H, Ma Y L, et al. Mechanical and Galvano-chemistry Property Variation within Dissimilar Metal Weld between 1Cr18Ni9Ti and 1Cr13 Stainless Steel[J]. Journal of Materials Science & Technology, 2010, 26(5):477.
[15]
Yu C, Qi Z C, Yu H, et al. Microstructural and Mechanical Properties of Hot Roll Bonded Titanium Alloy/Low Carbon Steel Plate[J]. Journal of Materials Engineering and Performance, 2018, 27(4):1664.
[15]
Yu C, Qi Z C, Yu H, et al. Microstructural and Mechanical Properties of Hot Roll Bonded Titanium Alloy/Low Carbon Steel Plate[J]. Journal of Materials Engineering and Performance, 2018, 27(4):1664.
[16]
Mohebbi M S, Rezayat M, Parsa M H, et al. The impact of Nb on dynamic microstructure evolution of an Nb-Ti microalloyed steel[J]. Materials Science & Engineering A, 2018, 723:194.
[16]
Mohebbi M S, Rezayat M, Parsa M H, et al. The impact of Nb on dynamic microstructure evolution of an Nb-Ti microalloyed steel[J]. Materials Science & Engineering A, 2018, 723:194.
[17]
Dey I, Chandra S, Saha R, et al. Effect of Nb micro-alloying on microstructure and properties of thermo-mechanically processed high carbon pearlitic steel[J]. Materials Characterization, 2018, 140:45.
[17]
Dey I, Chandra S, Saha R, et al. Effect of Nb micro-alloying on microstructure and properties of thermo-mechanically processed high carbon pearlitic steel[J]. Materials Characterization, 2018, 140:45.
[18]
Xie Z J, Shang C J, Wang X L, et al. Microstructure-property relationship in a low carbon Nb-B bearing ultra-high strength steel by direct-quenching and tempering[J], Materials Science & Engineering A, 2018, 727:200.
[18]
Xie Z J, Shang C J, Wang X L, et al. Microstructure-property relationship in a low carbon Nb-B bearing ultra-high strength steel by direct-quenching and tempering[J], Materials Science & Engineering A, 2018, 727:200.
[19]
Medeiros F F P, Silva A G P, Souza C P. Synthesis of niobium carbide at low temperature and its use in hardmetal[J], Powder Technology, 2002, 126:155.
[19]
Medeiros F F P, Silva A G P, Souza C P. Synthesis of niobium carbide at low temperature and its use in hardmetal[J], Powder Technology, 2002, 126:155.
[20]
Karmakar A, Biswas S, Mukherjee S, et al. Effect of composition and thermo-mechanical processing schedule on the microstructure, precipitation and strengthening of Nb-microalloyed steel[J]. Materials Science & Engineering A, 2017, 690:158.
[20]
Karmakar A, Biswas S, Mukherjee S, et al. Effect of composition and thermo-mechanical processing schedule on the microstructure, precipitation and strengthening of Nb-microalloyed steel[J]. Materials Science & Engineering A, 2017, 690:158.
[21]
Xia Q X, Xiao G F, Long H, et al. A study of manufacturing tubes with nano/ultrafine grain structure by stagger spinning[J]. Materials and Design, 2014, 59:516.
[21]
Xia Q X, Xiao G F, Long H, et al. A study of manufacturing tubes with nano/ultrafine grain structure by stagger spinning[J]. Materials and Design, 2014, 59:516.
[22]
Wieczerzal K, Bala P, Dziurka R, et al. The effect of temperature on the evolution of eutectic carbides and M7C3→M23C6 carbides reaction in the rapidly solidified Fe-Cr-C alloy[J]. Journal of Alloys and Compounds, 2017, 698:673.
[22]
Wieczerzal K, Bala P, Dziurka R, et al. The effect of temperature on the evolution of eutectic carbides and M7C3→M23C6 carbides reaction in the rapidly solidified Fe-Cr-C alloy[J]. Journal of Alloys and Compounds, 2017, 698:673.
[23]
Barnes N, Clark S, Seetharaman S, et al. Growth mechanism of primary needles during the solidification of chromium carbide overlays[J]. Acta Materialia, 2018, 151: 356.
[23]
Barnes N, Clark S, Seetharaman S, et al. Growth mechanism of primary needles during the solidification of chromium carbide overlays[J]. Acta Materialia, 2018, 151: 356.
[24]
Woydt M, Huang S, Vleugels J, et al.Potentials of niobium carbide (NbC) as cutting tools and for wear protection[J]. International Journal of Refractory Metals & Hard Materials, 2018, 72:380.
[24]
Woydt M, Huang S, Vleugels J, et al.Potentials of niobium carbide (NbC) as cutting tools and for wear protection[J]. International Journal of Refractory Metals & Hard Materials, 2018, 72:380.
[25]
Montenegro P, Gomes J, Rego R, et al. Potential of niobium carbide application as the hard phase in cutting tool substrate[J]. International Journal of Refractory Metals & Hard Materials, 2018, 70:116.
[25]
Montenegro P, Gomes J, Rego R, et al. Potential of niobium carbide application as the hard phase in cutting tool substrate[J]. International Journal of Refractory Metals & Hard Materials, 2018, 70:116.
[26]
Jiang S H, Wang H, Wu Y, et al. Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation[J]. Nature, 2017, 0:1.
[26]
Jiang S H, Wang H, Wu Y, et al. Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation[J]. Nature, 2017, 0:1.
[27]
Long X Y, Zhang F C, Yang Z N, et al. Study on microstructures and properties of carbide-free and carbide-bearing bainitic steels[J]. Materials Science & Engineering A, 2018, 715:10.
[27]
Long X Y, Zhang F C, Yang Z N, et al. Study on microstructures and properties of carbide-free and carbide-bearing bainitic steels[J]. Materials Science & Engineering A, 2018, 715:10.
[28]
Pariente IF, Belzunce F J, Riba C. Mechanical strength and fracture tough-ness of high chromium white cast iron[J]. Materials Science and Technology, 2008, 24:981.
[28]
Pariente IF, Belzunce F J, Riba C. Mechanical strength and fracture tough-ness of high chromium white cast iron[J]. Materials Science and Technology, 2008, 24:981.
[29]
Jena P S M, Sahu J K, Rai R K, et al. Influence of duplex ferritic-austenitic matrix on two body abrasive wear behaviour of high chromium white cast iron[J]. Wear, 2018, 406-407:140.
[29]
Jena P S M, Sahu J K, Rai R K, et al. Influence of duplex ferritic-austenitic matrix on two body abrasive wear behaviour of high chromium white cast iron[J]. Wear, 2018, 406-407:140.
30
] Wu D, Wang F M, Cheng J, et al. Effects of Nb and Tempering Time on Carbide Precipitation Behavior and Mechanical Properties of Cr-Mo-V Steel for Brake Discs[J]. steel research international, 2018, 89:1700491.
30
] Wu D, Wang F M, Cheng J, et al. Effects of Nb and Tempering Time on Carbide Precipitation Behavior and Mechanical Properties of Cr-Mo-V Steel for Brake Discs[J]. steel research international, 2018, 89:1700491.
[31]
Ren F C, Chen F, Chen J, et al. Hot deformation behavior and processing maps of AISI 420 martensitic stainless steel[J]. Journal of Manufacturing Processes, 2018, 31:640.
[31]
Ren F C, Chen F, Chen J, et al. Hot deformation behavior and processing maps of AISI 420 martensitic stainless steel[J]. Journal of Manufacturing Processes, 2018, 31:640.