Influence of microstructure and M/A island evolution on toughness of pipeline steel under controlled cooling process
NIU Yan-long1, LIU Qing-you1, JIA Shu-jun1, TONG Shuai1, WANG Bing1, REN Yi2
1. Institute of Structural Steels, Central Iron and Steel Research Institute, Beijing 100081, China; 2. State Key Laboratory of Metal Materials and Applications for Marine Equipment, Anshan 114009, Liaoning, China
Abstract:In order to study the influence of microstructures,volume percent and length/width ratio of M/A islands on low temperature toughness of pipeline steels,the multiscale means including optical microscope(OM),scanning electron microscopy (SEM),electron back scattering diffraction (EBSD) and transmission electron microscopy (TEM) were used. The results showed that the microstructure of three different cooling process was the same and all contained of acicular ferrite (AF) +quasi-polygonal ferrite (QF) +M/A island+grain bainite(GB). However,with the increase of cooling rate,the microstructure was refined remarkably,and the effective grain size decreased from 3.21 to 2.88 μm,the volume percent of M/A islands decreased from 11.2% to 5.8%,and the length/width ratio of M/A islands also decreased from 3.5 to 1.2. When the temperature was above -40 ℃,the low temperature toughness of pipeline steel increased greatly with the decrease of effective grain size and decrease of M/A island size and length/width ratio. However,when the temperature decreased to -80--60 ℃,the circular M/A islands dominated by martensite tended to embrittle and fracture,resulting in the lowest impact toughness,when the volume percent and the length/width ratio of M/A islands and were the lowest. However,the low temperature toughness of pipeline steel was not directly related to the percentage of large angle grain boundaries. For the high strength pipeline steel in this experiment,when the cooling process was 20 ℃/s,the M/A volume percent was about 9.8%,and the length/width ratio is 2.5,the material had excellent comprehensive toughness.
牛延龙, 刘清友, 贾书君, 童帅, 汪兵, 任毅. 控冷工艺下组织及M/A岛对管线钢韧性的影响[J]. 钢铁, 2020, 55(6): 91-100.
NIU Yan-long, LIU Qing-you, JIA Shu-jun, TONG Shuai, WANG Bing, REN Yi. Influence of microstructure and M/A island evolution on toughness of pipeline steel under controlled cooling process. Iron and Steel, 2020, 55(6): 91-100.
[1] 张振永,孟献强,孙学军,等. 中俄东线站场工艺管道用高钢级低温钢管韧性指标[J]. 油气储运,2018,37(4):435.(ZHANG Zhen-yong,MENG Xian-qiang,SUN Xue-jun,et al. Toughness index of low-temperature pipe of high steel grade used for the process pipelines at the station of China-Russia eastern natural gas pipeline[J]. Oil and Gas Storage and Transportation,2018,37(4):435.) [2] Layus P,Kah P,Martikainen J,et al. European and russian metals for arctic offshore structures[J]. Proceedings of the Twenty-third (2013) International Offshore and Polar Engineering,2013,55(2):242. [3] 段贺,单以银,杨柯,等. X80低温用高强度管线钢的工艺与组织性能试验[J]. 钢铁,2020,55(2):103. (DUAN He,SHAN Yi-yin,YANG Ke,et al. Experimental on process,microstructure and mechanical properties of X80 high strength pipeline steel for low temperature[J]. Iron and Steel,2020,55(2):103.) [4] Hara T,Shinohara Y,Asahi H,et al. Effects of microstructure and texture on DWTT properties for high strength line pipe steels[J]. International Pipeline Conference,2006,16(2):1. [5] Hwang B,Lee C G,Kim C J. Low-temperature toughening mechanism in thermomechanical processed high-strength low-alloy steels[J]. Metallurgical and Materials Transactions A,2011,42(3):717. [6] KANG Jian,LIN Cheng-ning,YUAN Guo,et al. Improvement of strength and toughness for hot rolled low-carbon bainitic steel via grain refinement and crystallographic texture[J]. Materials Letters,2016(175):157. [7] 李成良,黄远坚,温志红. Q620D钢板连续冷却相变行为和回火工艺[J]. 钢铁,2018,53(4):78. (LI Cheng-liang,HUANG Yuan-jian,WEN Zhi-hong. Continuous cooling transformation behavior and tempering process of Q620D steel plate[J]. Iron and Steel,2018,53(4):78.) [8] 李旭. Q690E高强度工程机械用钢冲击韧性分析[J]. 轧钢,2018,35(4):22.(LI Xu. Analysis of impact toughness of Q690E high strength engineering machinery steel[J]. Steel Rolling,2018,35(4):22.) [9] 阮红志,赵爱民,赵征志,等. 高钢级X100管线钢中的M-A岛[J]. 北京科技大学学报,2013,35(4):474.(RUAN Hong-zhi,ZHAO Ai-min,ZHAO Zheng-zhi,et al. M-A island in high grade X100 pipeline steel[J]. Journal of University of Science and Technology Beijing,2013,35(4):474.) [10] 贾书君,段琳娜,刘清友. 高钢级管线钢中M/A组元的控制工艺[J]. 材料热处理学报,2016,37(3):82.(JIA Shu-jun,DUAN Lin-na,LIU Qing-you. Controlling process of M/A constituents in high grade pipeline steel[J]. Transactions of Materials and Heat Treatment,2016,37(3):82.) [11] 王超,娄号南,王丙兴,等. 合金元素对大线能量焊接用钢组织性能的影响[J]. 钢铁,2018,53(6):85. (WANG Chao,LOU Hao-nan,WANG Bing-xing,et al. Effect of alloying elements on microstructure and properties of high heat input welding steel[J]. Iron and Steel,2018,53(6):85.) [12] 郭锦,史佳新,陈雨来. 快速冷却前停留时间对微合金钢相变的作用[J]. 钢铁,2018,53(5):62. (GUO Jin,SHI Jia-xin,CHEN Yu-lai. Effect of delay time before rapid cooling on transformation of micro-alloyed steel[J]. Iron and Steel,2018,53(5):62.) [13] 齐亮,彭凯,周君,等. TMCP工艺对X100管线钢M/A岛的影响[J]. 材料导报,2016,30(1):95.(QI Liang,PENG Kai,ZHOU Jun,et al. Effect of TMCP on M/A islands of X100 pipeline steel[J]. Materials Review,2016,30(1):95.) [14] 徐锋,孔君华,徐进桥,等. MA对高钢级厚壁X80管线钢性能影响的研究[J]. 石油管材与仪器,2015,32(3):33.(XU Feng,KONG Jun-hua,XU Jin-qiao,et al. The study of MA impact on the performance of X80 pipeline steel with high grade thick wall[J]. Petroleum Tubular Goods and Instruments,2015,32(3):33.) [15] HU S P,GUO Z. The strength and toughness behavior of acicular ferrite steel prepared by thermo-mechanical control process[J]. Journal of Plasticity Engineering,2010,32(17):93. [16] Shin S Y,Hwang B,Lee S,et al. Effects of notch shape and specimen thickness on drop-weight tear test properties of API X70 and X80 line-pipe steels[J]. Metallurgical and Materials Transactions A,2007,38A(3):537. [17] Hong S,Shin S Y,Lee S,et al. Effects of specimen thickness and notch shape on fracture modes in the drop weight tear test of API X70 and X80 pipeline steels[J]. Metallurgical and Materials Transactions A,2011,42A(9):2619. [18] 曾燕屏,朱鹏宇,仝珂. 显微组织对X70管线钢力学性能的影响[J]. 材料热处理学报,2015,36(3):45. (ZENG Yan-ping,ZHU Peng-yu,TONG Ke. Effect of microstructure on mechanical properties of X70 pipeline steels[J]. Transactions of Materials and Heat Treatment,2015,36(3):45.) [19] 牛延龙,刘清友,贾书君,等. X80级高强低合金管线钢组织与冲击韧性[J]. 钢铁,2019,54(2):67. (NIU Yan-long,LIU Qing-you,JIA Shu-jun,et al. Microstructure and impact toughness of X80 high strength low alloy pipeline steel[J]. Iron and Steel,2019,54(2):67.) [20] 赵金华,王学强,康健,等. 超快冷工艺下X80管线钢的DWTT裂纹扩展行为[J]. 材料研究学报,2017,31(10):728.(ZHAO Jin-hua,WANG Xue-qiang,KANG Jian,et al. Crack propagation behavior during DWTT for X80 pipeline steel processed via ultra-fast cooling technique[J]. Chinese Journal of Material Research,2017,31(10):728.) [21] ZHAO J,HU W,WANG X,et al. Effect of microstructure on the crack propagation behavior of micro-alloyed 560 MPa(X80) strip during ultra-fast cooling[J]. Materials Science and Engineering,2016(666):214. [22] 刘清友,贾书君,任毅. 高钢级厚壁管线钢低温断裂韧性控制技术研究[J]. 焊管,2019,42(7):39.(LIU Qing-you,JIA Shu-jun,REN Yi. Research on controlled technology of low temperature fracture toughness on high-grade thick-wall pipeline steels[J]. Welded Pipe and Tube,2019,42(7):39.) [23] 张伟卫,池强,王鹏,等. 微观组织对管线钢落锤性能的影响研究[J]. 焊管,2018,41(12):15. (ZHANG Wei-wei,CHI Qiang,WANG Peng,et al. The influence of microstructure on DWTT performance for pipeline steel[J]. Welded Pipe and Tube,2018,41(12):15.) [24] 聂文金,尚成嘉,关海龙,等. 铁素体/贝氏体(F/B)双相钢组织调控及其抗变形行为分析[J]. 金属学报,2012,48(3):298. (NIE Wen-jin,SHANG Cheng-jia,GUAN Hai-long,et al. Control of microstructures of ferrite/bainite (F/B) dual-phase steels and analysis of their resistance to deformation behavior[J]. Acta Metallurgica Sinica,2012,48(3):298.) [25] 杨旭宁,康永林,于浩,等. X70针状铁素体管线钢中M/A岛的工艺控制[J]. 轧钢,2007,24(4):7.(YANG Xu-ning,KANG Yong-lin,YU Hao,et al. Process control of M/A island in X70 acicular ferrite pipeline steel[J]. Steel Rolling,2007,24(4):7.) [26] 周民,杜林秀,衣海龙,等. X80管线钢落锤撕裂性能的影响因素分析[J]. 钢铁研究学报,2009,21(9):33.(ZHOU Min,DU Lin-xiu,YI Hai-long,et al. Factors affecting DWTT property of X80 pipeline steel[J]. Journal of Iron and Steel Research,2009,21(9):33.)